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贺德华(HE Dehua) 教授,博士生导师
通讯地址:北京海淀清华大学 化学系 (邮编100084)
电子邮件:hedeh@mail.tsinghua.edu.cn
目前讲授的课程:多相催化动力学,化学动力学
课题组招收博士后研究人员,欢迎联系
教育背景
1982.1,华东理工大学(石油化工), 学士
1987.3,日本冈山大学(合成化学),硕士
1990.3,日本东京工业大学(化学环境工程),博士
工作履历
1991-1994,日本相模中央化学研究所,研究人员
1995-现在,清华大学化学系,教师
1999-2000,日本地球环境产业技术研究所,客座研究人员
2003-2004,美国弗吉尼亚大学,访问学者
学术兼职
中国化学会络合催化专业委员会,委员(2003 - )
研究领域
多相、均相催化(主要研究一碳化学、燃料化学、生物质转化、精细化学品合成以及环境治理中的催化剂和催化反应工艺。)
研究概况
目前的研究课题:
甲烷活化转化(部分氧化制合成气以及制甲醇/甲醛催化剂)的研究
CO/H2异构合成制异构碳四烃、低碳烯烃催化剂与催化工艺的研究
合成气制低碳醇催化剂与催化工艺的研究
生物质来源丙三醇催化氢解制丙二醇催化剂的研究
高碳烯烃氢甲酰化新型催化剂与催化工艺的研究
Rh-P、Pd-P均相催化剂固载化新方法的研究
学术成果
部分代表论文:
Wei Zhou, Yuming Li, Dehua He*, Substrate influences on activity and stability of SBA-15–Pr-anchored Rh–P complex catalysts for olefin hydroformylation,Applied Catalysis A: General 377: 114–120, 2010
Lan Ma, Dehua He*, Influence of catalyst pretreatment on catalytic properties and performances of Ru–Re/SiO2 in glycerol hydrogenolysis to propanediols, Catalysis Today 149: 148–156, 2010
Yongge Bai, Dehua He*, Shaohui Ge, Huimin Liu, Jinyao Liu, Wei Huang, Influences of preparation methods of ZrO2 support and treatment conditions of Cu/ZrO2 catalysts on synthesis of methanol via CO hydrogenation, Catalysis Today 149: 111–116, 2010
Wei Zhou, Dehua He*, A facile method for promoting activities of ordered mesoporous silica-anchored Rh-P complex catalysts in 1-octene hydroformylation, Green Chemistry, 11: 1146-1154, 2009.
Lan Ma, Dehua He*, Hydrogenolysis of Glycerol to Propanediols Over Highly Active Ru-Re Bimetallic Catalysts, Topics in Catalysis, 52: 834-844, 2009.
Lan Ma, Qingrong Peng, Dehua He*, Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene, Catalysis Letters, 130: 137-146, 2009.
Wei Zhou, Dehua He*, Anchoring RhCl(CO)(PPh3)2 to -PrPPh2 Modified MCM-41 as Effective Catalyst for 1-Octene Hydroformylation, Catalysis Letters, 127: 437-443, 2009.
Yueqin Song, Huimin Liu, Shuqiang Liu, Dehua He*, Partial Oxidation of Methane to Syngas over Ni/Al2O3 Catalysts Prepared by a Modified Sol-Gel Method, Energy & Fuels, 23: 1925-1930, 2009.
Lan Ma, Dehua He*, Effect of Rhenium Component and Preparation Methods of ZrO2 Support on Catalytic Performance of Ru-Re/ZrO2 for Glycerol Hydrogenolysis, Chinese Journal of Catalysis, 30: 471-478, 2009
Shuqiang Liu, Yueqin Song, Dehua He*, Zhanping Li, Partial Oxidation of Methane to Syngas over Cr2O3 Catalysts, Chemical Journal of Chinese Universities-Chinese, 30: 106-112, 2009.
Lan Ma, Dehua He*, Zhanping Li, Promoting effect of rhenium on catalytic performance of Ru catalysts in hydrogenolysis of glycerol to propanediol, Catalysis Communications, 9: 2489-2495, 2008.
Wei Zhou, Dehua He*, Lengthening alkyl spacers to increase SBA-15-anchored Rh-P complex activities in 1-octene hydroformylation, Chemical Communications, 44: 5839-5841, 2008.
Shaohui Ge, Dehua He*, Zhanping Li, A Mesoporous Ce0.5Zr0.5O2 Solid Solution Catalyst for CO Hydrogenation to iso-C4 Hydrocarbons, Catalysis Letters, 126: 193-199, 2008.
Yingwei Li, Dehua He*, Shaohui Ge, Rongjun Zhang, Qiming Zhu, Effects of CO2 on Synthesis of Isobutene and Isobutane from CO2/CO/H2 Reactant Mixtures over Zirconia-based Catalysts, Applied Catalysis B: Environmental, 80: 72–80, 2008.
Yueqin Song, Dehua He*, Boqing Xu, Effects of Preparation Methods of ZrO2 Support on Catalytic Performances of Ni/ZrO2 Catalysts in Methane Partial Oxidation to Syngas, Applied Catalysis A: General, 337:19-28, 2008.
Zhihui Zhu, Dehua He*, CO Hydrogenation to iso-C4 Hydrocarbons over CeO2-TiO2 Catalysts, Fuel, 870: 2229–2235, 2008.
Yingwei Li, Dehua He*, Zhihui Zhu, Qiming Zhu, Properties of Sm2O3-ZrO2 Composite Oxides and Their Catalytic Performance in Isosynthesis, Applied Catalysis A: General, 319: 119~127, 2007.
Qingrong Peng, DehuaHe*, Hydroformylation of mixed octenes over immobilized Co-Ph3PO/PDMS/SiO2 catalyst, Catalysis Letters, 115(1-2): 19-22, 2007.
Lei Shi, Guoli Dong, Dehua He*, Influence of preparation parameters on catalytic performance of samaria in isosynthesis, Catalysis Communications, 8(3):359-365, 2007.
X. Zhang, Dehua He*, Qijian Zhang, Boqing Xu, Qiming Zhu, Comparative studies on direct conversion of methane to methanol/ formaldehyde over La–Co–O and ZrO2 supported molybdenum oxide catalysts, Topics in Catalysis, 32(3-4): 215 – 223, 2005.
Yingwei Li, Dehua He*, Qiming Zhu, Xin Zhang, Boqing Xu, Effects of redox and acid-base properties on the isosynthesis over ZrO2 based catalysts, Journal of Catalysis, 221:2:584-593, 2004.
Xin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Methanol from oxidation of methane over MoOx/ La-Co-oxide catalysts, Stud. Surf. Sci. Catal., 147: 541-546, 2004.
Xin Zhang, Dehua He*, Qijian Zhang, Qing Ye, Boqing Xu, Qiming Zhu, Selective oxidation of methane to formaldehyde over Mo/ZrO2 catalysts, Applied Catalysis A: General, 249(1): 107, 2003.
Yingwei Li, Dehua He*, Qijian Zhang, Qiming Zhu, Influence of reactor materials on i-C4 synthesis from CO hydrogenation over ZrO2 based catalysts, Fuel Processing Technology, 83(1-3): 39-48, 2003
Qijian Zhang, Dehua He*, Xin Zhang, Qiming Zhu, Shuiliang Yao, Direct Partial Oxidation of Methane to Methanol in a Specially Designed Reactor, ACS Sym. Ser. 852: Utilization of Greenhouse Gases, pp280-290, American Chemical Society Press: Washington DC, 2003.
Qijian Zhang, Dehua He*, Qiming Zhu, Recent Progress in Direct Partial Oxidation of Methane to Methanol, J.Nat.Cas.Chem., 12(2), P81-89, 2003.
Qijian Zhang, Dehua He*, Jinlu Li, Boqing Xu, Yu Liang, Qiming Zhu, Comparatively high yield methanol production from gas phase partial oxidation of methane, Applied Catalysis A: General, 224 (1-2): 201, 2002
Qijian Zhang, Dehua He*, Zhansheng Han, Boqing Xu, Qiming Zhu, Controlled Partial Oxidation of Methane to Methanol /formaldehyde over Mo-V-Cr-Bi-Si Oxide catalysts, Fuel, 81: 1599, 2002.
Yingwei Li, Dehua He*, Yubin Yuan, Zhenxing. Cheng, Qiming Zhu, Influence of Acidic and Basic Properties of ZrO2 Based Catalysts on Isosynthesis, Fuel, 81: 1611, 2002.
Dehua He*, Dongcheng Pang, Yu Chen, Lan Wei, Tong-en Wang, Jinyao Liu, Yan Liu, Qiming Zhu, Hydroformylation of C8 Olefins Catalyzed by Rhodium-Inorganic Ammonium Salt Systems, Catalysis Communications, 3 (9): 429-433, 2002.
Yingwei Li, Dehua He*, Zhenxing Cheng, Caili Su, JinluLi, Qiming Zhu, Effect of calcium salts on isoynthesis over ZrO2 catalysts, J. Molecular Catalysis A: Chemical, 175(1-2): 267, 2001.
Dehua He*, Dongcheng Pang, Yu Chen, Tong-en Wang, Yan Liu, Jinyao Liu, Qiming Zhu, Hydroformylation of Mixture of Isomeric Octenes to C9-Aldehydes Catalyzed by Rh-Phosphine Oxide Complexes, J. Molecular Catalysis A: Chemical, 174(1-2): 21, 2001.
Yingwei Li, Dehua He*, Yubin Yuan, Zhenxing Cheng, Qiming Zhu, Selective Formation of Isobutene from CO Hydrogenation over Zirconium Dioxide Based Catalysts, Energy and Fuels, 15: 1434, 2001.
Jinyao Liu, Jiangliu Shi, Dehua He, Qijian Zhang, Xiaohui Wu, Yu Liang, Qiming Zhu, Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction, Applied Catalysis A: General, 218: 113, 2001.
Dehua He*, Jinyao Liu, Yan Liu, Tong-en Wang, Dongcheng Pang, Yu Chen, Yu Liang, Qiming Zhu, Effects of Ammonium Salts as Additives in Rh-Ph3PO Catalytic System on Hydroformylation of Mixed Octenes, Catalysis Letters, 73(2-4): 221, 2001.
已授权(或公开)的专利:
用于合成气制异丁烯的助剂/氧化锆催化剂(中国专利) ZL 99121713.6 2003.5.21
从烯烃、一氧化碳和氢气合成醛的方法( 中国专利) ZL 00128279.4 2003.10.8
用于甲烷选择氧化合成甲醛的钴-镧-钼氧化物催化剂及其制备方法(中国专利) ZL02125911.9 2003.12.17
用于甲烷选择氧化合成甲醛的锆钼氧化物催化剂及其制备方法(中国专利) ZL02125912.7 2003.12.17
Process for synthesis of aldehydes from olefins, carbon monoxide and hydrogen(韩国专利) 10-0436594 2004.6.8
一种从天然气气相氧化直接合成甲醇的方法及其装置(中国专利) ZL 01120438.9 2004.2.11
一种制备异丁烯和异丁烷的方法(中国专利) ZL200310115541.0 2005.11.9
一种制备异辛烷的方法(中国专利) ZL200410009950.7 2006.6.7
从混合辛烯和合成气制造异壬醛的方法(中国专利) ZL200410062259.5 2007.3.7
一种氧化钐催化剂的制备及应用(中国专利) ZL200410012736.8 2007.8.22
一种从丙三醇直接加氢制备丙二醇的方法(中国专利) ZL200810103814.2 2009.1
一种从烯烃和合成气制造醛的方法(中国专利) 200710118593.1 公开中
一种CO加氢合成低碳混合醇催化剂的制备方法(中国专利) 200810105142.9 公开中
一种制备醛的固载化铑膦配合物催化剂的方法(中国专利) 200810226111.9 公开中
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